Red Light-Excitable Oxygen Sensing Materials Based on Platinum(II) and Palladium(II) Benzoporphyrins

Red Light-Excitable Oxygen Sensing Materials Based on Platinum(II) and Palladium(II) Benzoporphyrins
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DOI:
10.1021/ac801521v
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发表时间:
2008-12-15
影响因子:
7.4
通讯作者:
Klimant, I.
Klimant, I.
中科院分区:
化学1区
文献类型:
--
作者:
Borisov, S. M.;Nuss, G.;Klimant, I.

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新的光学氧传感材料利用高发光近红外铂(II)和钯(II)与苯并卟啉配合物。制备了基于聚苯乙烯的本体光极和基于聚(苯乙烯-嵌段-乙烯基吡咯烷酮)和聚砜的传感纳米珠,并对其进行了表征。新材料的多功能性得到了证明。其特点包括与大多数常见激励源的良好兼容性、高亮度和适用于皮下氧监测。
New optical oxygen-sensing materials make use of highly luminescent NIR platinum(II) and palladium(II) complexes with benzoporphyrins. Bulk optodes based on polystyrene and sensing nanobeads based on poly(styrene-block-vinylpyrrolidone) and polysulfone are prepared and characterized. The versatility of the new materials is demonstrated. The features include excellent compatibility with most common excitation sources, high brightness, and suitability for subcutaneous oxygen monitoring.