Nickel-Catalyzed C-H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes
Nickel-Catalyzed C-H Coupling with Allyl Phosphates: A Site-Selective Synthetic Route to Linear Allylarenes
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DOI：
10.1021/ol501707z
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发表时间：
2014-08-01
期刊：
影响因子：
5.2
通讯作者：
Zeng, Xiaoming
中科院分区：
文献类型：
--
作者：
Cong, Xuefeng;Li, Yuexuan;Zeng, Xiaoming
据报道，镍/膦催化剂可以有效地进行C-H烯丙化反应，烯丙基位置的选择性主要由空间效应决定。该反应为从易得的苯甲酰胺和烯丙基磷酸盐中选择性地制备直链烯丙基芳烃提供了一条简便和可预测的路线。
It is reported that a nickel/phosphine catalyst allows the C-H allylation to occur effectively with the allyl site selectivity predominantly governed by steric effects. This reaction provides a facile and predictable route for the selective preparation of linear allylarenes from readily available benzamides and allyl phosphates.