Diaquatris(pentane-2,4-dionato-O,O')holmium(III) monohydrate and diaquatris(pentane-2,4-dionato-O,O')holmium(III) 4-hydroxypentan-2-one solvate dihydrate
Diaquatris(pentane-2,4-dionato-O,O')holmium(III) monohydrate and diaquatris(pentane-2,4-dionato-O,O')holmium(III) 4-hydroxypentan-2-one solvate dihydrate
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Diaquatris(戊烷-2,4-二酮-O,O)钬(III)一水合物和diaquatris(戊烷-2,4-二酮-O,O)钬(III) 4-羟基戊-2-酮溶剂化物二水合物
DOI：
10.1107/s0108270199013566
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发表时间：
2000
期刊：
影响因子：
--
通讯作者：
Fred van het Schip
中科院分区：
文献类型：
--
作者：
H. Kooijman;Frank Nijsen;A. Spek;Fred van het Schip
标题化合物[Ho（C5H7O2）3（H2O）2]·H2O和[Ho（C5H7O2）3（H2O）2]·C5H8O2·2H2O的结构均为八配位反棱柱构型。这些结构的堆积由氢键分子的无限二维网络组成。在这两种结构中，发现HoIII络合物的相同氢键链。
The structures of the title compounds, [Ho(C5H7O2)3(H2O)2]·H2O and [Ho(C5H7O2)3(H2O)2]·C5H8O2·2H2O, both show an eight-coordinate holmium(III) ion in a square antiprismatic configuration. The packing of these structures consists of an infinite two-dimensional network of hydrogen-bonded molecules. In both structures, the same hydrogen-bonded chain of HoIII complexes is found.