Adsorption and desorption of Hg(II) by three typical soils around the chlor-alkali industry

Adsorption and desorption of Hg(II) by three typical soils around the chlor-alkali industry
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氯碱工业周边三种典型土壤对Hg(II)的吸附与解吸

DOI:
10.1080/10807039.2017.1331727
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发表时间:
2017-08
影响因子:
4.3
通讯作者:
Qi Y
Qi Y
中科院分区:
环境科学与生态学3区
文献类型:
--
作者:
Chen Yong;Zhang Wenxin;Hong Chenglin;Qi Yu;Hong CL;Qi Y

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采用间歇吸附实验研究了我国氯碱工业周边草甸土、潮土和灰漠土对Hg(Ⅱ)的吸附/解吸特性。结果表明,氯碱厂周围3种典型土壤对Hg(Ⅱ)的吸附量由大到小依次为:草甸土(4536.24 mg/kg)、潮土(1598.62 mg/kg)、灰漠土(1272.51 mg/kg)和土壤有机质对Hg(Ⅱ)的吸附有显著影响。动力学研究表明,三种土壤对汞的吸附均具有快速阶段和缓慢阶段的特征。Hg(Ⅱ)的吸附速率以潮土最高,其次是草甸土,灰漠土最低。研究结果对干旱区土壤污染控制与治理具有指导作用,为我国西北绿洲环境汞污染研究与综合治理提供参考。
A series of batch experiments were conducted to assess the adsorption/.desorption of Hg(II) within meadow soil, fluvo-aquic soil, and gray desert.soil around the chlor-alkali industry in China. Results demonstrated that.the descending order of the adsorptive capacity of Hg(II) to the three.typical soils around a chlor-alkali plant, i.e., meadow soil (4536.24 mg/.kg), fluvo-aquic soil (1598.62 mg/kg), gray desert soil (1272.51 mg/kg),.and the soil organic matter, had a significant role in Hg(II) adsorption..Kinetic studies revealed that the Hg adsorption in the three soils was.characterized with a fast stage and a slow stage. The Hg(II) adsorption.rates are the highest for the fluvo-aquic soil, followed by the meadow.soil, and then the gray desert soil. The results will play a guiding role in.arid-zone soil pollution control and treatment, which will be a reference.for the Northwest Oasis Environmental mercury pollution studies and.integrated control in China.
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