Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents.
Iron-catalyzed oxidative homo-coupling of aryl Grignard reagents.
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DOI：
10.1021/ol047509
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发表时间：
2005-01
期刊：
影响因子：
5.2
通讯作者：
T. Nagano;Tamio Hayashi
中科院分区：
文献类型：
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作者：
T. Nagano;Tamio Hayashi
[反应：见文]铁催化芳基格氏试剂的均偶联反应研制成功。在1-5 mol % FeCl3和1,2-二氯乙烷的存在下，各种芳基格氏试剂有效地转化为相应的对称双芳基。
[reaction: see text] Iron-catalyzed homo-coupling of aryl Grignard reagents was successfully developed. A variety of aryl Grignard reagents were efficiently converted into the corresponding symmetrical biaryls in the presence of 1-5 mol % FeCl3 and a stoichiometric amount of 1,2-dichloroethane.