Novel CdS/MOF Cathodic Photoelectrochemical (PEC) Platform for the Detection of Doxorubicin Hydrochloride and Gentamicin Sulfate
Novel CdS/MOF Cathodic Photoelectrochemical (PEC) Platform for the Detection of Doxorubicin Hydrochloride and Gentamicin Sulfate
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DOI：
10.1021/acsami.1c19481
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发表时间：
2021-12-08
影响因子：
9.5
通讯作者：
Wen, Guangming
中科院分区：
文献类型：
--
作者：
Dong, Wenxia;Li, Zhongping;Wen, Guangming
纳米材料的选择是光电化学（PEC）传感的关键。本文提出了一种新的阴极光电化学（PEC）检测盐酸阿霉素（Dox）和硫酸庆大霉素（CN）的方法。通过将硫化镉（CdS）非共价偶联到卟啉衍生的金属有机框架（CdS@PCN-224）来合成光电阴极。这种类型的组装为盐酸阿霉素和硫酸庆大霉素的组合创造了令人愉快的界面，从而产生良好的CdS@PCN-224供体-受体系统。与单一光电材料相比，其光电流前所未有地增强了9倍。这项研究可以为实现PCN-224在PEC传感方面的巨大潜力铺平道路。
Nanomaterial selection is critical for photoelectrochemical (PEC) sensing. In this report, a novel cathodic photoelectrochemical (PEC) strategy was proposed for the detection of doxorubicin hydrochloride (Dox) and gentamicin sulfate (CN). The photocathode was synthesized by noncovalently coupling cadmium sulfide (CdS) to the porphyrin-derived metal-organic framework (CdS@PCN-224). This type of assembly created a pleasant interface for the combination of doxorubicin hydrochloride and gentamicin sulfate, resulting in a good CdS@PCN-224 donor-acceptor system. When compared to a single optoelectronic material, its photocurrent is enhanced by unprecedented nine times. This research could pave the way for the realization of PCN-224's enormous potential in PEC sensing.