Highly stable keto-enamine salicylideneanilines
Highly stable keto-enamine salicylideneanilines
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DOI：
10.1021/ol0352714
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发表时间：
2003-10-16
期刊：
影响因子：
5.2
通讯作者：
MacLachlan, MJ
中科院分区：
文献类型：
--
作者：
Chong, JH;Sauer, M;MacLachlan, MJ
[图解]1，3，5-三甲酰基间苯三酚与苯胺衍生物反应，合成了高稳定的NH-水杨醛基苯胺。用X-射线单晶数据和核磁共振研究证实了NH型的存在。本文还报道了一种简便的三甲酰基间苯三酚的合成方法。
[GRAPHICS]Highly stable NH salicylideneanilines have been prepared by reaction of 1,3,5-triformylphloroglucinol with aniline derivatives. The NH form was confirmed by X-ray crystallographic data, as well as by NMR studies. A convenient one-step synthesis of triformylphloroglucinol is also reported.