Spectroscopy of Matrices and Thin Films with an Integrating Sphere

Spectroscopy of Matrices and Thin Films with an Integrating Sphere
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使用积分球对矩阵和薄膜进行光谱分析

DOI:
10.1366/0003702894203327
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发表时间:
1989
影响因子:
3.5
通讯作者:
Stephen R. Wilson
Stephen R. Wilson
中科院分区:
化学3区
文献类型:
--
作者:
E. Berger;D. W. T. Griffith;G. Schuster;Stephen R. Wilson

文献摘要

被引文献

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The paper describes a novel experimental approach to improving sensitivity to weak absorption in matrix isolation and thin film spectroscopy. The matrix or film is grown on the surface of an integrating sphere, in which the multiply reflected light correspondingly multipasses the sample film. The quantitative photometric behavior of the sphere is satisfactorily described by extending standard theory. Enhancement of absorption by a factor of at least 20 is possible and is demonstrated. The sphere has a number of useful advantages over other multipass techniques, particularly in matrix isolation spectroscopy.