Initial anticrossing between Stark manifold n and n+1 in Na

Initial anticrossing between Stark manifold n and n+1 in Na
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DOI:
10.1007/s00214-006-0158-5
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发表时间:
2006-08
影响因子:
1.7
通讯作者:
Yong Li
Yong Li
中科院分区:
化学4区
文献类型:
--
作者:
Yong Li

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我们提出了钠中 Stark 流形nandn+ 1 之间初始反交叉的位置和宽度的理论结果,该结果是通过使用从一种原子势模型中选择零场波函数的对角化方法获得的。这些结果可以为理解微波电离过程提供定量信息,其限速步骤可能是在这两个流形最外层状态之间的第一次交叉处执行的 thenton+1 跃迁。
We present the theoretical results for the positions and widths of the initial anticrossing between Stark manifoldnandn+ 1 in sodium, obtained by using the method of diagonalization in which zero-field wave functions are chosen from a kind of atomic potential model. These results can provide the quantitative information for understanding the microwave ionization process, whose rate-limiting step is probably thenton+ 1 transition performed at the first crossing between the outermost states of these two manifolds.