Enhancement of Guest-Responsivity by Mesocrystallization of Porous Coordination Polymers
Enhancement of Guest-Responsivity by Mesocrystallization of Porous Coordination Polymers
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通过多孔配位聚合物的介观结晶增强客体响应性
DOI：
10.1039/c7tc00751e
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发表时间：
2017
期刊：
影响因子：
--
通讯作者：
Masaaki Ohba
中科院分区：
文献类型：
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作者：
Akio Mishima;Tomomi Koshiyama;Jose A. Real;Masaaki Ohba
采用反胶束法制备了具有自旋跃迁的多孔配位聚合物{Fe（pz）[Pt（CN）4]}（1）的介晶，尺寸可控的介晶1保持了其多孔性和磁双稳性，并在固态和水悬浮态下均表现出比体相1更高的自旋态转换的客体响应性.
Mesocrystals of a porous coordination polymer {Fe(pz)[Pt(CN)4]} (1) showing spin transition were prepared by the reverse micelle method, and the size-controlled mesocrystal 1 kept its porous property and magnetic bistability and exhibited higher guest-responsivity with switching the spin state in both solid and aqueous suspension states than the bulk 1.