Gasification of Waste Tire with ZnO as an Oxidant for Solar Energy Utilization

Gasification of Waste Tire with ZnO as an Oxidant for Solar Energy Utilization
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ZnO作为氧化剂气化废轮胎用于太阳能利用

DOI:
10.3379/jmsjmag.22.s1_425
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发表时间:
1998
影响因子:
--
通讯作者:
Y. Tamaura
Y. Tamaura
中科院分区:
--
文献类型:
--
作者:
S. Yoshida;H. Amano;Y. Hosokawa;M. Tsuji;Y. Tamaura

文献摘要

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废轮胎(主要成分=碳)将被利用为一种有用的材料,通过聚光太阳能通过太阳能热化学气化成二氧化碳气体,将太阳能转化为化学能。在本文中,研究了使用 ZnO 作为氧供体在 1373K 红外炉中对废轮胎(C 86%,H 8.4%)的气化。 20秒后,轮胎样品中的大部分H2转化为分子H2和C~(H2:C~=62:29),71摩尔%的C气化为CO(36%)、C~(29%)、C2~(2%)和CO2(4%)。 CO 2 约为CO量的III 0 ,表明废轮胎中的碳可以有效地转化为气体燃料。在没有ZnO的实验中,C和H的气化转化率降低至碳的17%和氢的77%。废轮胎ZnO气化过程中放出的CO2量小于废轮胎燃烧过程中释放的CO2量。
Waste tire (main component = carbon) will be utilized as a useful material for conversion of solar energy into chemical energy by a solar thermochemical gasification into CO gas using concentrated solar energy. In the present paper, the gasification of a waste tire (C 86%, H 8.4%) was studied using ZnO as a donor of oxygen in the infrared furnace at 1373K. After 20 sec, most ofH2 in the tire sample was converted into molecular H2 and C~(H2:C~=62:29) and 71 mole% ofC was gasified to CO(36 %), C~(29 %), C2~(2 %), and CO2( 4 %). C02 was about III 0 of CO quantity, indicating that carbon in the waste tire can be converted effectively to gaseous fuels. In the experiment without ZnO, the conversion in the gasification of C and H were decreased to 17% for carbon and 77% for hydrogen. The volume of evolved CO2 in the gasification of waste tire with ZnO was less than in the combustion of waste tire.