Intermolecular Gold-Catalyzed Diastereo- and Enantioselective [2+2+3] Cycloadditions of 1,6-Enynes with Nitrones
Intermolecular Gold-Catalyzed Diastereo- and Enantioselective [2+2+3] Cycloadditions of 1,6-Enynes with Nitrones
复制标题
DOI：
10.1002/anie.201203507
复制
发表时间：
2012-01-01
影响因子：
16.6
通讯作者：
Liu, Rai-Shung
中科院分区：
文献类型：
--
作者：
Gawade, Sagar Ashok;Bhunia, Sabyasachi;Liu, Rai-Shung
去淘金：标题反应已被开发，并证明了一个广泛的底物范围，相对于1，6-烯炔和硝酮（见方案; DCE= 1，2-二氯乙烷，Tf=三氟甲磺酰基）。对映选择性版本的结果也被提出。
Going for gold: The title reaction has been developed and demonstrates a wide substrate scope with respect to the 1, 6-enynes and nitrones (see scheme; DCE= 1, 2-dichloroethane, Tf= trifluoromethanesulfonyl). The results for the enantioselective versions are also presented.