Molecular design of functional polymer surfaces
Molecular design of functional polymer surfaces
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DOI：
10.1002/polb.20157
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发表时间：
2004-08-15
影响因子：
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通讯作者：
Koberstein, JT
中科院分区：
文献类型：
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作者：
Koberstein, JT
提出了三个设计原则，允许功能聚合物表面的分子设计：表面分离，表面结构和表面重组。这些设计原则是通过描述模型末端功能聚合物的行为来说明的，这些行为准确地反映了基本上所有可能的线性功能聚合物结构的一般行为。本文描述了设计原理的几个应用，以说明它们如何用于为实际问题提供分子工程解决方案。这些应用包括优化功能性聚合物结构，用于生产粘合剂和释放表面，通过使用功能性添加剂来降低涂层的表面张力来抑制脱湿，以及创建具有选择性粘附性能的智能聚合物表面。(C) 2004 Wiley期刊有限公司
Three design principles are presented that allow for the molecular design of functional polymer surfaces: surface segregation, surface structure, and surface reorganization. These design principles are illustrated by a description of the behavior of model end-functional polymers that accurately reflect the general behavior of essentially all possible linear functional polymer architectures. Several applications of the design principles are described to show how they may be used to provide molecular engineering solutions for problems of practical interest. The applications include the optimization of functional polymer architectures for producing adhesive and release surfaces, the suppression of dewetting by the use of functional additives to lower the surface tension of a coating, and the creation of smart polymer surfaces with selective adhesion properties. (C) 2004 Wiley Periodicals, Inc.