Critical behavior of brittle‐ductile transition of polymers
Critical behavior of brittle‐ductile transition of polymers
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DOI：
10.1002/polb.21411
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发表时间：
2008-04
期刊：
影响因子：
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通讯作者：
Wei Jiang;Yuexin Hu;Jinghua Yin
中科院分区：
文献类型：
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作者：
Wei Jiang;Yuexin Hu;Jinghua Yin
We report that the brittle-ductile transition of polymers induced by temperature exhibits critical behavior. When t close to 0, the critical surface to surface interparticle distance (IDc) follows the scaling law: IDc ∝ t−v, where t = 1 − T/T (T and T are the test temperature and brittle-ductile transition temperature of matrix polymer, respectively) and v = 2/D. It is clear that the scaling exponent v only depends on dimension (D). For 2, 3, and 4 dimension, v = 1, 2/3, and 1/2 respectively. The result indicates that the IDc follows the same scaling law as that of the correlation length (ξ), when t approach to zero. © 2008 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 46: 766–769, 2008
