Syntheses of Some Condensation Polymers by Phase-Transfer Catalyzed Polycondensation
Syntheses of Some Condensation Polymers by Phase-Transfer Catalyzed Polycondensation
复制标题
相转移催化缩聚合成某些缩聚物
DOI：
--
复制
发表时间：
1981
期刊：
影响因子：
--
通讯作者：
Y. Imai
中科院分区：
文献类型：
--
作者：
Y. Imai
摘要对使用季铵盐、季鏻盐、冠醚和聚乙二醇等相转移催化剂的两相缩聚反应进行了基础研究，为合成各种缩聚物提供了有用的信息。我们成功地合成了各种类型的缩聚物，如芳香族聚磺酸酯和聚膦酸酯，芳香族聚醚，脂肪族和芳香族聚硫化物，和高分子量的碳-碳链聚合物，通过相转移催化缩聚反应，从芳香族二磺酰氯，膦酸二氯化物，活化的芳香族二氯化物，和脂肪族二卤化物的组合，与双酚，脂肪族和芳香族二硫醇，和活性亚甲基化合物。两相缩聚反应一般在室温或更高温度下，在与水不混溶的有机溶剂-碱性水溶液体系中进行。总之，这种缩聚方法提供了一个高度通用和方便。
Abstract Fundamental studies on the two-phase polycondensation using various phase-transfer catalysts such as quaternary ammonium and phosphonium salts, crown ethers, and poly(ethylene glycol)s yielded information useful for the synthesis of a variety of condensation polymers. We successfully synthesized various types of condensation polymers such as aromatic polysulfonates and polyphosphonates, aromatic polyethers, aliphatic and aromatic polysulfides, and carbon-carbon chain polymers of high molecular weights by the phase-transfer catalyzed polycondensation from combinations of aromatic disulfonyl chlorides, phosphonic di-chlorides, activated aromatic dichlorides, and aliphatic dihalides, with bisphenols, aliphatic and aromatic dithiols, and active methylene compounds. The two-phase polycondensation was generally carried out in a water-immiscible organic solvent-aqueous alkaline solution system at room temperature or above. In conclusion, this method of polycondensation offers a highly versatile and conv...