Some Approaches to Novel Molten Salt Electrochemical Processes
Some Approaches to Novel Molten Salt Electrochemical Processes
复制标题
新型熔盐电化学过程的一些方法
DOI：
10.5796/electrochemistry.68.88
复制
发表时间：
2000
期刊：
影响因子：
2.5
通讯作者：
Y. Ito
中科院分区：
文献类型：
--
作者：
Y. Ito
This review article describes some selected novel molten salt electrochemical processes which have been challenged by the author and his co−workers．Metallic Na is produced with high current efficiency by the electrolysis of molten NaCl−ZnCl20r NaOH usingβ一alumina diaphragm。Two kinds of chlorine recovery from HCl gas are possible by electrochemical processes in molten LiCl−KCL A novel SiH4production method has been proposed by the use of Si electrode in a molten LiCl−KC1−LiH system，N2gas is cathodically reduced to form N3皿 ion in molten LiCl−KCl，which encourages the author to develop new applications，6．8．，Li−N2thermally regenera− tive fuel cell and thermogalvanic cell．Electrochemical implantation of nitrogen to form various metal nitrides is possible by the use of anodic reaction of N3−ion in a molten LiCl−KCl−Li3N system．Electrochemical implanta− tion and displantation can be applied to form transition metal−rare earth alloys in molten LiCl−KCl containing rare earth chloride．Finally，as non−conventional electrochemical reactions，discharge electrolysis to form fine metal or carbon particles and electrochemical plantation of Zr on ceramics are introduced． κ6ッ防跳