Effect of B-Ions Substitution in [(K1/2Bi1/2)-(Na1/2Bi1/2)](Ti-B)O3 System with B=Zr, Fe1/2Nb1/2, Zn1/3Nb2/3 or Mg1/3Nb2/3
Effect of B-Ions Substitution in [(K1/2Bi1/2)-(Na1/2Bi1/2)](Ti-B)O3 System with B=Zr, Fe1/2Nb1/2, Zn1/3Nb2/3 or Mg1/3Nb2/3
复制标题
B=Zr、Fe1/2Nb1/2、Zn1/3Nb2/3 或 Mg1/ 的 [(K1/2Bi1/2)-(Na1/2Bi1/2)](Ti-B)O3 体系中 B 离子取代的影响
DOI：
--
复制
发表时间：
1995
期刊：
影响因子：
--
通讯作者：
Takuro Ikeda Takuro Ikeda
中科院分区：
文献类型：
--
作者：
Y. Yamada;T. Akutsu;H. Asada;K. Nozawa;Shinji Hachiga;Takeshi Kurosaki;Osamu Ikagawa;H. Fujiki;Katsuhiro Hozumi;T. Kawamura;Takashi Amakawa;K. Hirota;Takuro Ikeda Takuro Ikeda
Phase relationship in the [(K1/2Bi1/2)1-y (Na1/2Bi1/2)y ](Ti1-x Bx )O3 system with B=Zr, Fe1/2Nb1/2, Zn1/3Nb2/3 or Mg1/3Nb2/3 has been investigated by dielectric measurement and X-ray diffractometry. All of the bi-binary systems were solid-soluble throughout the entire composition range. With increasing y and x, ferroelectric Curie point decreased and the ε-T curve became flat. Composition dependence of the transition temperature was examined by varying x or y. Phase diagrams were mostly determined at room temperature on square diagrams except for a restricted area in the vicinity of (Na1/2B1/2)ZrO3, which involved a tetragonally distorted phase and could not be accounted for. The ferroelectric tetragonal phase was confined within a narrow range of x<0.1 and the rhombohedral phase was dominant in all of the systems studied here.
