Flow‐drift technique for ion mobility and ion‐molecule reaction rate constant measurements. II. Positive ion reactions of N+, O+, and H2+ with O2 and O+ with N2 from thermal to [inverted lazy s]2 eV
Flow‐drift technique for ion mobility and ion‐molecule reaction rate constant measurements. II. Positive ion reactions of N+, O+, and H2+ with O2 and O+ with N2 from thermal to [inverted lazy s]2 eV
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用于离子淌度和离子分子反应速率常数测量的流动漂移技术 II。
DOI：
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发表时间：
1973
期刊：
影响因子：
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通讯作者：
A. Schmeltekopf
中科院分区：
文献类型：
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作者：
M. Mcfarland;D. Albritton;F. Fehsenfeld;E. Ferguson;A. Schmeltekopf
在一个新的流动漂移管装置上测量了正离子-分子反应N++O2→ NO++O→ O2++N，N2++O2 → O2++N2，O++O2→ O2++O，O++N2→ NO++N。反应（a）、（B）和（c）是从热能到质心中约2 eV的离子动能测量的。从0.3- 3eV离子动能测量反应（d）。的数据同意与以前的热值在低能量和同意与束数据在最高的能量。在除（a）以外的所有反应的情况下，随着能量的增加，速率常数最初减小，然后增加。
The positive ion‐molecule reactions N++O2→ NO++O→ O2++N, N2++O2→ O2++N2, O++O2→ O2++O, O++N2→ NO++N, were measured in a newly constructed flow‐drift tube apparatus. Reactions (a), (b), and (c) were measured from thermal energy to approximately 2 eV ion kinetic energy in the center of mass. Reaction (d) was measured from 0.3–3 eV ion kinetic energy. The data agree well with previous thermal values at low energies and agree well with beam data at the highest energy. In the case of all the reaction except (a), there is an initial decrease of the rate constant with increasing energy followed by an increase.