Improved Performance in Polymer-Fullerene Blend Photovoltaic Cells by Insertion of C60 Interlayer

Improved Performance in Polymer-Fullerene Blend Photovoltaic Cells by Insertion of C60 Interlayer
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DOI:
10.1080/15421400701545445
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发表时间:
2007-09
影响因子:
0.7
通讯作者:
R. Maeda;K. Fujita;T. Tsutsui
R. Maeda;K. Fujita;T. Tsutsui
中科院分区:
化学4区
文献类型:
--
作者:
R. Maeda;K. Fujita;T. Tsutsui

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我们证明了通过在活性层和上电极之间插入C60夹层来增强聚合物:PCBM共混物光伏电池的器件性能。通过旋涂聚合物{(聚(2-甲氧基-5-(2′-乙基-己氧基)-1,4-亚苯基亚乙烯基)(MEH-PPV)或(聚(3-己基噻吩)(P3 HT)和富勒烯衍生物[5,6]-苯基-C61-丁酸甲酯(PCBM))}制备活性层,然后沉积C60夹层和LiF/Al电极。与没有C60层的电池相比,具有C60夹层的两种聚合物电池显示出功率转换效率的显著增加。
We demonstrate the enhancement of the device performance in polymer:PCBM blend photovoltaic cells by insertion of C60 interlayer between the active layer and the upper electrode. The active layer was fabricated by spin coating of a polymer {(poly(2-methoxy-5-(2′-ethyl-hexyloxy)-1,4-phenylene vinylene)(MEH-PPV) or (poly(3-hexylthiopene)(P3HT) and fullerene derivative [5,6]-phenyl-C61-butyric acid methyl ester(PCBM)}, then the C60 interlayer and LiF/Al electrode were deposited. The both polymer cells with C60 interlayer showed significant increase in the power conversion efficiency compared to cells without the C60 layer.