Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds
Cationic copper(I) complexes as efficient precatalysts for the hydrosilylation of carbonyl compounds
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DOI：
10.1021/om0600487
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发表时间：
2006-04-24
期刊：
影响因子：
2.8
通讯作者：
Nolan, SP
中科院分区：
文献类型：
--
作者：
Díez-González, S;Scott, NM;Nolan, SP
合成并表征了含两个氮杂环卡宾的新型阳离子铜配合物。这些空气和水分稳定的配合物被发现是高度活跃的对氢化硅烷化的酮与不同的空间拥挤，醛（甚至烯醇化的），和酯。
Novel cationic copper complexes bearing two N-heterocyclic carbenes (NHCs) have been synthesized and fully characterized. These air- and moisture-stable complexes were found to be highly active toward the hydrosilylation of ketones with varying steric congestion, aldehydes (even enolizable ones), and esters.