SYNTHESIS OF STABLE ALPHA,ALPHA'-BIS(CARBOXYMETHYL) SUBSTITUTED NITROXIDES VIA AN ORIGINAL DIANION-BASED STRATEGY
SYNTHESIS OF STABLE ALPHA,ALPHA'-BIS(CARBOXYMETHYL) SUBSTITUTED NITROXIDES VIA AN ORIGINAL DIANION-BASED STRATEGY
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DOI：
10.1039/c39950001029
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发表时间：
1995-05-21
影响因子：
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通讯作者：
PIERRE, JL
中科院分区：
文献类型：
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作者：
EINHORN, J;EINHORN, C;PIERRE, JL
新的稳定的氮氧自由基，类似于克里思（四甲基哌啶-N-氧基），其中两个α，α '甲基在形式上被酯官能团取代，通过二烯醇化物化学，然后脱保护-氧化序列制备。
New stable nitroxides, analogous to TEMPO (tetramethylpiperidine-N-oxyl) where two alpha,alpha' methyl groups are formally replaced by ester functions, are prepared via dienolate chemistry followed by a deprotection-oxidation sequence.