Proton transfer to photoexcited aromatic compounds in solution
Proton transfer to photoexcited aromatic compounds in solution
复制标题
质子转移到溶液中的光激发芳香族化合物
DOI：
10.1163/156856793x00037
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发表时间：
1994
影响因子：
3.3
通讯作者：
G. Zhang
中科院分区：
文献类型：
--
作者：
P. Wan;G. Zhang
本文综述了近三十年来在光激发芳香族化合物芳香环质子转移方面的研究进展。据预测，在单线态激发态下芳香环的碱性要比在基态下高得多。然而，直到最近才对这一领域进行了系统和定量的研究。这篇综述将突出现有的重要新见解，并表明在芳环的激发态酸碱化学中还有更多的东西需要学习。
This review paper will summarize work carried out during the last thirty years in the area of proton transfer to the aromatic ring of photoexcited aromatic compounds. The aromatic ring has been predicted to be much more basic in the singlet excited state than in the ground state. However, only recently has there been systematic and quantitative studies in this area. This review will highlight the significant new insights now available and demonstrate that there is much more to be learned in the excited state acid-base chemistry of aromatic rings.