A ring size-selective reduction of lactones using Sml2 and H2O
A ring size-selective reduction of lactones using Sml2 and H2O
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DOI：
10.1021/ja078137d
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发表时间：
2008-01-30
影响因子：
15
通讯作者：
Procter, David J.
中科院分区：
文献类型：
--
作者：
Duffy, Lorna A.;Matsubara, Hiroshi;Procter, David J.
Sml（2）-H_2O还原体系对六元内酯的选择性优于其它类型的内酯和酯。实验和计算研究表明，起源的选择性在于最初的电子转移到内酯羰基。
The Sml(2)-H2O reducing systems shows complete selectivity for six-membered lactones over other classes of lactone and esters. Experimental and computational studies suggest that the origin of the selectivity lies in the initial electron-transfer to the lactone carbonyl.