A triarylphosphine ligand bearing dodeca(ethylene glycol) chains: enhanced efficiency in the palladium-catalyzed Suzuki-Miyaura coupling reaction.
A triarylphosphine ligand bearing dodeca(ethylene glycol) chains: enhanced efficiency in the palladium-catalyzed Suzuki-Miyaura coupling reaction.
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DOI：
10.1021/ol900578g
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发表时间：
2009-04
期刊：
影响因子：
5.2
通讯作者：
Tetsuaki Fujihara;Shohei Yoshida;J. Terao;Y. Tsuji
中科院分区：
文献类型：
--
作者：
Tetsuaki Fujihara;Shohei Yoshida;J. Terao;Y. Tsuji
合成了一种含十二碳链的膦配体，并将其用于钯催化的Suzuki-Miyaura偶联反应。该系统被发现是非常有效的使用未活化的芳基氯化物作为基板。
A new phosphine bearing dodeca(ethylene glycol) chains has been synthesized and employed as a ligand in the palladium-catalyzed Suzuki-Miyaura coupling reaction. The system was found to be highly effective using unactivated aryl chlorides as the substrate.