Generation of a triplet diradical from a donor-acceptor cross conjugate upon acid-induced electron transfer.
Generation of a triplet diradical from a donor-acceptor cross conjugate upon acid-induced electron transfer.
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DOI：
10.1039/b804999h
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发表时间：
2008-08
影响因子：
4.9
通讯作者：
M. Sandberg;O. Nagao;Zhikun Wu;M. Matsushita;T. Sugawara
中科院分区：
文献类型：
--
作者：
M. Sandberg;O. Nagao;Zhikun Wu;M. Matsushita;T. Sugawara
通过双质子化增强对奎诺二亚胺单元的电子受体能力，导致质子诱导的分子内电子从给体单元到交叉共轭受体的转移，从而可逆地产生基态三重态双自由基。
Enhancement of the electron acceptor ability of a para-quinodiimine unit by double protonation leads to the proton-induced intramolecular electron transfer from the donor unit to the cross-conjugated acceptor, giving rise to ground state triplet diradical reversibly.