Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts
Visible light-mediated oxidative decarboxylation of arylacetic acids into benzyl radicals: addition to electron-deficient alkenes by using photoredox catalysts
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DOI：
10.1039/c3cc44438d
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发表时间：
2013-01-01
影响因子：
4.9
通讯作者：
Nishibayashi, Yoshiaki
中科院分区：
文献类型：
--
作者：
Miyake, Yoshihiro;Nakajima, Kazunari;Nishibayashi, Yoshiaki
苯环对位含氨基的芳基乙酸与烯烃在一定量的过渡金属多吡啶配合物光催化剂的催化下，在可见光照射下反应顺利进行，通过氧化脱羧制得相应的苯甲基化产物。
Reactions of arylacetic acids bearing an amino group at the para-position in the benzene ring with alkenes in the presence of a catalytic amount of transition metal polypyridyl complexes as photocatalysts under visible light illumination proceed smoothly to give the corresponding benzylated products via oxidative decarboxylation in good to high yields.