Palladium- or Proton-induced Submicro Spherical Aggregation of Macrocyclic Amphiphiles in Aqueous Solution
Palladium- or Proton-induced Submicro Spherical Aggregation of Macrocyclic Amphiphiles in Aqueous Solution
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水溶液中钯或质子诱导的大环两亲物的亚微米球形聚集
DOI：
10.1039/c3dt51827b
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发表时间：
2013
影响因子：
4
通讯作者：
M. Shionoya
中科院分区：
文献类型：
--
作者：
S. Tashiro;R. Kubota;M. Kawagoe;M. Shionoya
已发现合成的两亲分子在水介质中可以在许多长度尺度上自组装成各种结构，如胶束、小泡、柱状和片状。本文报道了阳离子诱导的六氮杂环番在水中的聚集。用多种光谱和显微方法观察到了Pd2+或质子诱导的亚微米级球形聚集体的形成。
Synthetic amphiphiles have been found to self-assemble into a variety of structures such as micelles, vesicles, cylinders and lamellae in aqueous media over many length scales. We report herein cation-induced aggregation of hexaaza-cyclophanes in water. Pd2+- or proton-induced formation of submicro spherical aggregates was observed by several spectroscopic and microscopic methods.