THE STRUCTURE AND PROPERTIES OF INORGANIC POLYMERIC PHOSPHATES
THE STRUCTURE AND PROPERTIES OF INORGANIC POLYMERIC PHOSPHATES
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DOI：
10.1002/pi.4980110402
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发表时间：
1979-01-01
期刊：
影响因子：
--
通讯作者：
RAY, NH
中科院分区：
文献类型：
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作者：
RAY, NH
一些最古老的无机聚合物是聚磷酸盐，托马斯·格雷厄姆 (Thomas Graham) 于 1833 年合成聚磷酸钠 1 比任何合成有机聚合物的发现早了近一个世纪。 Tamman 于 1892 年描述了第一种合成的结晶聚合物，2 他将其命名为 Kurrol 盐，以纪念他的同名合作者。然而，尽管 Fleitmann 和 Hennenberg 3 早在 1845 年就假设存在一系列同系长链聚磷酸盐，但这些化合物直到 1940 年左右才被普遍认为是高分子量聚合物，当时现代技术的出现使得证明它们的溶液含有具有数千个通过氧连接在一起的磷原子的阴离子。大多数聚磷酸盐所源自的结构单元 1 是四面体，但只有 3-连接，因为第四个氧原子无法连接到另一个原子，除非利用该氧上的两个剩余电子。这种连接是在化合物中形成的
Some of the oldest inorganic polymers are polyphosphates, and the synthesis of sodium polyphosphate by Thomas Graham in 1833 1 pre-dates the discovery of any synthetic organic polymer by nearly a century. The first crystalline polymer to be synthesised was described by Tamman in 1892, 2 who named it Kurrol's salt in recognition of his collaborator of that name. However, even though Fleitmann and Hennenberg 3 postulated the existence of a homologous series of long-chain polyphosphates as early as 1845, these compounds were not universally recognised as high-molecular weight polymers until about 1940, when the advent of modern techniques made it possible to demonstrate that their solutions contain anions having several thousands of phosphorus atoms linked together through~ xygen.~ The structural unit 1 from which the majority of polyphosphates are derived is tetrahedral but only 3-connective, since the fourth oxygen atom is not available for linking to another atom except by utilising both of the remaining electrons on that oxygen. Such linkages are formed in compounds with