High-performance PdNi alloy structured in situ on monolithic metal foam for coalbed methane deoxygenation via catalytic combustion.
High-performance PdNi alloy structured in situ on monolithic metal foam for coalbed methane deoxygenation via catalytic combustion.
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DOI：
10.1039/c5cc04389a
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发表时间：
2015-07
影响因子：
4.9
通讯作者：
Qiaofei Zhang;Xin‐Ping Wu;Guofeng Zhao;Yakun Li;Chunzheng Wang;Ye Liu;Xue-qing Gong;Yong Lu
中科院分区：
文献类型：
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作者：
Qiaofei Zhang;Xin‐Ping Wu;Guofeng Zhao;Yakun Li;Chunzheng Wang;Ye Liu;Xue-qing Gong;Yong Lu
通过电沉积Pd纳米颗粒在ni泡沫表面，然后原位活化，为煤层气脱氧定制了一种单片Ni-foam@PdNi（合金）催化剂。实验和理论研究一致表明，原位成形的PdNi合金具有较高的活性/选择性、良好的稳定性和消振性。
A monolithic Ni-foam@PdNi(alloy) catalyst is tailored for coalbed methane deoxygenation via galvanically depositing Pd nanoparticles on a Ni-foam surface followed by in situ activation. Experimental and theoretical studies unanimously reveal that the in situ formed PdNi alloy contributes to high activity/selectivity, good stability and oscillation elimination.