A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation.
A non-heme iron(III) complex with porphyrin-like properties that catalyzes asymmetric epoxidation.
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DOI：
10.1021/ja304219s
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发表时间：
2012-08
影响因子：
15
通讯作者：
Takashi Niwa;M. Nakada
中科院分区：
文献类型：
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作者：
Takashi Niwa;M. Nakada
在这份报告中，我们描述了一个铁（III）的配合物含有一个基于咔唑的三齿配体，催化高不对称环氧化（E）-烯烃在室温下。非血红素铁（III）配合物具有五配位三角双锥结构，其二电子氧化态具有与铁卟啉类似的电子结构。
In this report, we describe an iron(III) complex containing a carbazole-based tridentate ligand that catalyzes highly enantioselective asymmetric epoxidation of (E)-alkenes at room temperature. The non-heme iron(III) complex has a five-coordinated trigonal-bipyramidal structure, and its two-electron oxidized state has the similar electronic structure as that of iron porphyrins.