Coal tar dissolution in water-miscible solvents : experimental evaluation
Coal tar dissolution in water-miscible solvents : experimental evaluation
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DOI:
10.1021/es00049a025
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发表时间:
1993
影响因子:
11.4
通讯作者:
C. Peters;R. Luthy
中科院分区:
文献类型:
--
作者:
C. Peters;R. Luthy
Coal tar, a dense nonaqueous phase liquid (NAPL), is a common subsurface contaminant at sites of former manufactured gas plants. A proposed remediation technology is water-miscible solvent extraction, which requires understanding of the effect of water-miscible solvents on the solubility of coal tar. This study investigated this effect and the extent to which multicomponent coal tar could be represented as a pseudocomponent in thermodynamic modeling. The coal tar used in this study showed a predominance of polycyclic aromatic hydrocarbons nvith no single compound accounting for more than 4% (nvt). The bulk solubility of coal tar in water was estimated to be 16 mg/L using composition data and Raoult's law assumption for aqueous solubility