An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology.
An open-framework rutile-type magnesium isonicotinate and its structural analogue with an anatase topology.
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DOI：
10.1039/c2dt31394d
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发表时间：
2013-01
影响因子：
4
通讯作者：
Tingzhi Liu;Daibing Luo;Dingguo Xu;Hongmei Zeng;Zhien Lin
中科院分区：
文献类型：
--
作者：
Tingzhi Liu;Daibing Luo;Dingguo Xu;Hongmei Zeng;Zhien Lin
在溶剂热条件下合成了两种新的光致发光镁基配位聚合物Mg（int）（2）·H2O（1）和Mg（nt）（2）（2）。结构分析表明，他们有不同的3，6-连接的金红石型和锐钛矿型拓扑结构的框架，分别。化合物1在去除其客体分子后保持稳定，并且其表现出弱铁电行为。
Two new photoluminescent magnesium-based coordination polymers, Mg(int)(2)·H(2)O (1) and Mg(nt)(2) (2), were synthesized under solvothermal conditions. Structural analyses reveal that they have different 3,6-connected frameworks with rutile- and anatase-type topologies, respectively. Compound 1 remains stable after the removal of its guest molecules and it exhibits weak ferroelectric behavior.