Acetone: a solvent or a reagent depending on the addition order in SET-LRP
Acetone: a solvent or a reagent depending on the addition order in SET-LRP
复制标题
DOI：
10.1039/c8py01331d
复制
发表时间：
2018-11
影响因子：
4.6
通讯作者：
Adrián Moreno;Ja̅nis Lejnieks;M. Galià;Gerard Lligadas;V. Percec
中科院分区：
文献类型：
--
作者：
Adrián Moreno;Ja̅nis Lejnieks;M. Galià;Gerard Lligadas;V. Percec
取决于在丙酮/水混合物中进行的两相SET-LRP期间向反应混合物中的添加顺序，丙酮可以用作溶剂或用作被CuBr 2溴化的试剂以提供亲电溴丙酮引发剂以及羟醛缩合产物。
Depending on the order of addition to the reaction mixture during biphasic SET-LRP performed in acetone/water mixtures, acetone can serve as a solvent or as a reagent brominated by CuBr2 to provide the electrophilic bromoacetone initiator as well as aldol condensation products.