The Lewis Base Stabilized Parent Arsanylborane H2AsBH2NMe3
The Lewis Base Stabilized Parent Arsanylborane H2AsBH2NMe3
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DOI：
10.1002/chem.201302110
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发表时间：
2013-09-02
影响因子：
4.3
通讯作者：
Scheer, Manfred
中科院分区：
文献类型：
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作者：
Marquardt, Christian;Adolf, Ariane;Scheer, Manfred
完全氢取代的砷基硼烷：在一锅反应中以高产率和纯度合成了前所未有的刘易斯碱稳定的砷基硼烷H2 AsBH 2·NMe 3单体母体化合物。以类似的方式合成类似的膦基硼烷。在H2 AsBH 2-NMe 3上进行了一系列不同的反应，以显示其广泛的反应性模式。
Exclusively hydrogen‐substituted arsanylboranes: The synthesis of the unprecedented Lewis base stabilized monomeric parent compound of the arsanylborane H2AsBH2⋅ NMe3 was achieved in a one‐pot reaction in high yield and purity. The analogous phosphanylborane was synthesized in a similar manner. A series of different reactions was performed on H2AsBH2⋅ NMe3 to show its broad reactivity pattern.