Size-selective and reversible encapsulation of single small hydrocarbon molecules by a cavitand-porphyrin species.
Size-selective and reversible encapsulation of single small hydrocarbon molecules by a cavitand-porphyrin species.
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DOI：
10.1002/anie.200500732
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发表时间：
2005-06
影响因子：
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通讯作者：
J. Nakazawa;J. Hagiwara;Maki Mizuki;Y. Shimazaki;F. Tani;Y. Naruta
中科院分区：
文献类型：
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作者：
J. Nakazawa;J. Hagiwara;Maki Mizuki;Y. Shimazaki;F. Tani;Y. Naruta
（图中所示）一种可容纳的主体：一种新的胶囊状主体分子，如图所示的空穴卟啉，可逆地包裹了比丙烷小的单个烃分子（见图）。除乙炔外，结合亲和力与客体烃的大小呈负相关。
(Figure Presented) An accommodating host: A new capsule-shaped host molecule, the cavitand-porphyrin shown, reversibly encapsulates single hydrocarbon molecules smaller than propane (see picture). With the exception of acetylene, the binding affinities are inversely correlated with the size of the guest hydrocarbons.