Investigation of Suitable Templates for One-Pot-Synthesized Cu-SAPO-34 in NOx Abatement from Diesel Vehicle Exhaust
Investigation of Suitable Templates for One-Pot-Synthesized Cu-SAPO-34 in NOx Abatement from Diesel Vehicle Exhaust
复制标题
一锅法合成 Cu-SAPO-34 在柴油车尾气氮氧化物减排中的适用模板研究
DOI：
10.1021/acs.est.0c01743
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发表时间：
2020
影响因子：
11.4
通讯作者：
He Hong
中科院分区：
文献类型：
--
作者：
Du Jinpeng;Shi Xiaoyan;Shan Yulong;Zhang Wenshuo;Yu Yunbo;Shan Wenpo;He Hong
The control of NOxemission from diesel vehicles is of great importance to the environment, and Cu-SAPO-34 is considered to be an effective catalyst for the abatement of NOxfrom diesel vehicles. Along with catalytic activity, hydrothermal stability is a key property for NOxabatement catalysts. The attack of Cu species and framework atoms by H2O may result in activity loss under both low/high temperature humid conditions, which are inevitable in practical application. Therefore, apart from good catalytic activity, hydrothermal stability under both low/high temperatures for Cu-SAPO-34 is also critical for NOxcontrol in diesel vehicles. Three Cu-SAPO-34 samples were prepared by a one-pot hydrothermal method using propylamine, triethylamine, and morpholine, with Cu-TEPA (tetraethylenepentamine) as the cotemplate. The NH3-SCR activity and the effects of hydrothermal aging at 70 and 800 °C on these Cu-SAPO-34 samples were investigated. The type of cotemplate can affect the Si and Cu species in one-pot-synthesized Cu-SAPO-34 catalysts, so that the catalytic activity as well as the low/high temperature hydrothermal stability is affected by the choice of template. Generally speaking, Cu-SAPO-34 prepared using PA as cotemplate showed superior catalytic activity and hydrothermal stability under low/high temperatures compared with the other two catalysts, which makes PA a more suitable template for one-pot-synthesized Cu-SAPO-34 for use in NOxabatement from diesel vehicle exhaust.
