Development of controlled reactions using an element-based design of azaporphyrinoid materials
Development of controlled reactions using an element-based design of azaporphyrinoid materials
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DOI：
10.1142/s1088424622300014
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发表时间：
2022-07-29
影响因子：
1.5
通讯作者：
Furuyama，Taniyuki
中科院分区：
文献类型：
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作者：
Furuyama，Taniyuki
酞菁(PC)及其相关的大环化合物(氮杂卟啉)是现代材料化学中著名的人工染料。已经提出了几种微调它们的光学/电化学/芳香族性质的策略。PC的多样性实现了新的功能，这些功能可以帮助创新方法来调整和改善不同材料的性能。有机合成产生了各种各样的有机分子。在本文中，作者描述了在有机合成中发展控制反应的两种方法：合成新型PC的控制反应和使用PC的控制反应。特别是，作者提出了一种“基于元素”的设计策略，通过一个简单的合成过程来获得独特的性能。这一策略允许微调近红外(NIR)区域(700-1000 nm)的光学性质。这些创新将为近红外光的灵活应用创造更多机会
Phthalocyanines (Pcs) and related macrocycles (azaporphyrinoids) are well-known artificial dyes in modern material chemistry. Several strategies for fine-tuning their optical/electrochemical/aromatic properties have been proposed. The diversity of Pcs enables novel functionalities that can assist in innovative approaches to tune and improve the properties of diverse material. Organic synthesis yields a wide array of organic molecules. Herein, the author describes two methods for developing controlled reactions in organic synthesis: controlled reactions to produce novel Pcs and controlled reactions using Pcs. In particular, the author proposes an “element-based” design strategy to obtain unique properties using a simple synthetic procedure. This strategy permits the fine-tuning of optical properties in the near-infrared (NIR) region (700–1000 nm). These innovations should create further opportunities for flexible applications of NIR light