High nuclearity structurally – related Mn supertetrahedral T4 aggregates
High nuclearity structurally – related Mn supertetrahedral T4 aggregates
复制标题
高核结构相关的 Mn 超四面体 T4 聚集体
DOI：
10.1039/d1cc01815a
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发表时间：
2021
影响因子：
4.9
通讯作者：
Papatriantafyllopoulou, Constantina
中科院分区：
文献类型：
--
作者：
Skordi, Katerina;Anastassiades, Antonis;Fournet, Adeline D.;Kumar, Rahul;Schulze, Michael;Wernsdorfer, Wolfgang;Christou, George;Nastopoulos, Vassilios;Perlepes, Spyros P.;Papatriantafyllopoulou, Constantina
在锰羧酸盐化学中同时使用1，3-丙二醇和二-2-吡啶基酮提供了三种新的结构相关的[Mn 24]和[Mn 23]簇。它们基于纳米尺寸的超四面体T4 Mn/O结构核，并且在低于3.5K下表现出缓慢的磁化弛豫。
The simultaneous employment of 1,3-propanediol and di-2-pyridyl ketone in Mn carboxylate chemistry has provided access to three new, structurally-related [Mn24] and [Mn23] clusters. They are based on nanosized supertetrahedal T4 Mn/O structural cores and exhibit slow relaxation of magnetization below 3.5 K.