Oxygen atom transfer with organofunctionalized polyoxovanadium clusters: O-atom vacancy formation with tertiary phosphanes and deoxygenation of styrene oxide
Oxygen atom transfer with organofunctionalized polyoxovanadium clusters: O-atom vacancy formation with tertiary phosphanes and deoxygenation of styrene oxide
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DOI：
10.1039/c9sc02882j
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发表时间：
2019-07
期刊：
影响因子：
8.4
通讯作者：
Brittney E. Petel;R. L. Meyer;W. Brennessel;E. Matson
中科院分区：
文献类型：
--
作者：
Brittney E. Petel;R. L. Meyer;W. Brennessel;E. Matson
我们报道了一个罕见的例子，氧原子转移（OAT）从多金属氧酸盐簇到一系列叔膦，然后OAT从氧化苯乙烯转移到还原支架，导致苯乙烯的形成。
We report a rare example of oxygen atom transfer (OAT) from a polyoxometalate cluster to a series of tertiary phosphanes followed by OAT from styrene oxide to the reduced scaffold, resulting in the formation of styrene.