One-Pot Synthesis of Imines from Nitroaromatics and Alcohols by Tandem Photocatalytic and Catalytic Reactions on Degussa (Evonik) P25 Titanium Dioxide
One-Pot Synthesis of Imines from Nitroaromatics and Alcohols by Tandem Photocatalytic and Catalytic Reactions on Degussa (Evonik) P25 Titanium Dioxide
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DOI：
10.1021/am508769x
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发表时间：
2015-02-18
影响因子：
9.5
通讯作者：
Hirai, Takayuld
中科院分区：
文献类型：
--
作者：
Hirakawa, Hiroaki;Katayama, Miyu;Hirai, Takayuld
Degussa（Evonik）P25 TiO 2（金红石和金红石颗粒的混合物）在室温下在含有硝基芳香族化合物的醇中的光照射（λ> 300 nm）以非常高的产率（80 - 96%）产生相应的亚胺。然而，其它市售的金红石型或金红石型TiO 2颗粒表现出非常低的产率（
Photoirradiation (lambda > 300 nm) of Degussa (Evonik) P25 TiO2, a mixture of anatase and rutile particles, in alcohols containing nitroaromatics at room temperature produces the corresponding imines with very high yields (8096%). Other commercially available anatase or rutile TiO2 particles, however, exhibit very low yields (