Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.

Facile preparation of homo- and hetero-dimetallic complexes with a 4-phosphino-substituted NHC ligand. Toward the design of multifunctional catalysts.
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使用 4-膦基取代的 NHC 配体轻松制备同二金属和异二金属配合物。

DOI:
10.1002/asia.201000856
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发表时间:
2011
期刊:
Chemistry, an Asian journal
影响因子:
--
通讯作者:
Bertrand,Guy
Bertrand,Guy
中科院分区:
--
文献类型:
--
作者:
Mendoza-Espinosa,Daniel;Donnadieu,Bruno;Bertrand,Guy

文献摘要

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合成了一系列由 4-膦基取代的 NHC 配体支持的双金属配合物。这种稳定配体的使用减少了合成步骤的数量,并允许将多种金属组合引入配合物中。
A series of bimetallic complexes have been synthesized that are supported by a 4‐phosphino‐substituted NHC ligand. The use of this stable ligand reduces the number of synthetic steps and allows for a wide range of metal combinations to be introduced into the complexes.