Formation of Trinuclear Complexes by Addition of Mercury(II) Halides and Gold(I) Halides to Pt2(.mu.-dpm)2(CN)2
Formation of Trinuclear Complexes by Addition of Mercury(II) Halides and Gold(I) Halides to Pt2(.mu.-dpm)2(CN)2
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DOI:
10.1021/ic00104a025
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发表时间:
1994-12
影响因子:
4.6
通讯作者:
D. Toronto;A. Balch
中科院分区:
文献类型:
--
作者:
D. Toronto;A. Balch
The reactivity of the metal—metal bond of Pt2 (M-dpm) 2X2 and Pd2 (w-dpm) 2X2, 1 (dpm is bis (diphenylphosphino) methane), have been shown to insert directly into the Pt—Pt bond of 1 to produce the stable trimetallic clusters Pt2 (M-HgCl2J (w-dpm) 2-Cl2, 2, 8 and Pt2 («-AuClj (w-dpm) 2Cl2, 3.9 Attempts at inserting