Coronene nanophase within coordination spheres: increased solubility of C60.
Coronene nanophase within coordination spheres: increased solubility of C60.
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DOI：
10.1021/ja910836h
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发表时间：
2010-02
影响因子：
15
通讯作者：
Kosuke Suzuki;K. Takao;Sota Sato;M. Fujita
中科院分区：
文献类型：
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作者：
Kosuke Suzuki;K. Takao;Sota Sato;M. Fujita
一个4.6 nm大小的配位球在其核心限制了24个侧链晕苯分子。受限的晕苯分子是流体，形成一种永远不会大量存在的液体“晕苯纳米液滴”。C（60）以高的局部浓度溶解在该纳米溶剂中。
A 4.6 nm-sized coordination sphere confines 24 pendant coronene molecules at its core. The confined coronene molecules are fluid, forming a liquid "coronene nanodroplet" that could never exist in bulk. C(60) dissolves in this nano solvent with a high local concentration.