Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water.
Formic acid acting as an efficient oxygen scavenger in four-electron reduction of oxygen catalyzed by a heterodinuclear iridium-ruthenium complex in water.
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DOI：
10.1021/ja104486h
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发表时间：
2010-08
影响因子：
15
通讯作者：
S. Fukuzumi;Takeshi Kobayashi;T. Suenobu
中科院分区：
文献类型：
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作者：
S. Fukuzumi;Takeshi Kobayashi;T. Suenobu
一种异双核铱钌配合物[Ir（III）（Cp*）（H（2）O）（bpm）Ru（II）（bpy）（2）]（SO（4））（2）（Cp* = η（5）-五甲基-β-吡啶基，bpm = 2，2 '-联嘧啶，bpy = 2，2'-联吡啶）作为一种有效的催化剂，通过在室温下用甲酸在水中还原O（2）来除去溶解的O（2）。
A heterodinuclear iridium-ruthenium complex [Ir(III)(Cp*)(H(2)O)(bpm)Ru(II)(bpy)(2)](SO(4))(2) (Cp* = eta(5)-pentamethyl-cyclopentadienyl, bpm = 2,2'-bipyrimidine, bpy = 2,2'-bipyridine) acts as an effective catalyst for removal of dissolved O(2) by the four-electron reduction of O(2) with formic acid in water at an ambient temperature.