Recent progress of electronic materials based on 2,1,3-benzothiadiazole and its derivatives: synthesis and their application in organic light-emitting diodes

Recent progress of electronic materials based on 2,1,3-benzothiadiazole and its derivatives: synthesis and their application in organic light-emitting diodes
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2,1,3-苯并噻二唑及其衍生物电子材料的合成及其在有机发光二极管中的应用研究进展

DOI:
10.1007/s11426-020-9901-4
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发表时间:
2020-12
期刊:
Science China Chemistry
影响因子:
--
通讯作者:
Wai-Yeung Wong
Wai-Yeung Wong
中科院分区:
其他
文献类型:
--
作者:
Youming Zhang;Jun Song;Junle Qu;Peng-Cheng Qian;Wai-Yeung Wong

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2,1,3-苯并噻二唑(BT)及其衍生物是发展光致发光化合物中非常重要的受体单元,适用于有机发光二极管、有机太阳能电池和有机场效应晶体管的分子结构。由于BT及其衍生物具有很强的吸电子能力,以BT及其衍生物为单位核的分子构筑通常可以改善有机材料的电子性质。本文综述了BT及其衍生物与各种聚合物、小分子和金属络合物的合成及其在有机发光二极管中的应用。此外,还讨论了基于这些核的分子设计规则。
2,1,3-Benzothiadiazole (BT) and its derivatives are very important acceptor units used in the development of photoluminescent compounds and are applicable for the molecular construction of organic light-emitting diodes, organic solar cells and organic field-effect transistors. Due to their strong electron-withdrawing ability, construction of molecules with the unit core of BT and its derivatives can usually improve the electronic properties of the resulting organic materials. In this contribution, we review the synthesis of various polymers, small molecules and metal complexes with BT and its derivatives and their applications in organic light-emitting diodes. Furthermore, the molecular design rules based on these cores are discussed.
萘并噻二唑基%20近红外%20发射器%20with%20a%20光致发光%20Quantum%20产率%20of%2060%%20in%20Neat%20Film%20and%20外部%20Quantum%20效率%20of%20up%20to%203.9%%20in%
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