Chiroptical Properties of an alternatingly functionalizedcellotriose bearing two porphyrin groups
Chiroptical Properties of an alternatingly functionalizedcellotriose bearing two porphyrin groups
复制标题
带有两个卟啉基团的交替官能化纤维三糖的手性光学特性
DOI：
10.1039/c2cc30805c
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发表时间：
2012
期刊：
影响因子：
--
通讯作者：
T. Rosenau
中科院分区：
文献类型：
--
作者：
Sakakibara;K.;F.Nakatsubo;AS.D.French;T. Rosenau
首次揭示了源自连接在纤维三糖骨架上的 O-6 和 O''-6 位点的双卟啉的右手性。这种纤维三糖被提议作为交替功能化纤维素的模型，由于其手性和刚性主链效应，其在光电子学和分子受体方面的应用具有广阔的前景。
Right-handedness derived from bisporphyrins attached to a cellotriose backbone at O-6 and O′′-6 positions is revealed for the first time. This cellotriose is proposed as a model of alternatingly functionalized cellulosics, which have promising properties for applications in optoelectronics and molecular receptors owing to the chirality and rigid backbone effects.