Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization
Effective stereoselective approach to substituted 1,4-dioxane-2,5-diones as prospective substrates for ring-opening polymerization
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DOI：
10.1016/j.mencom.2018.01.020
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发表时间：
2018-01-01
影响因子：
1.9
通讯作者：
Nifant'ev, Ilya E.
中科院分区：
文献类型：
--
作者：
Lozhkin, Boris A.;Shlyakhtin, Andrey V.;Nifant'ev, Ilya E.
Intramolecular cyclization of alpha-bromoacyl derivatives of alpha-hydroxy acids affords 1,4-dioxane-2,5-diones. The method is suitable to obtain mono- and disubstituted products, the latter being formed stereoselectively as (S,S)-diastereomers, as confirmed by DFT modeling.
