Comparative investigation on the enthalpy relaxation of four amorphous pentose isomers
Comparative investigation on the enthalpy relaxation of four amorphous pentose isomers
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DOI:
10.1007/s10973-013-3217-x
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发表时间:
2013
影响因子:
4.4
通讯作者:
C. Gao;Bin Ye;Bin Jiang;Xiang-nong Liu
中科院分区:
文献类型:
--
作者:
C. Gao;Bin Ye;Bin Jiang;Xiang-nong Liu
The enthalpy relaxation of the pentose isomers (d-xylose,d-ribose,l-arabinose, andd-arabinose) was investigated in terms of the Tool–Narayanaswamy–Moynihan and Adam–Gibbs–Vogel models using differential scanning calorimetry. Single set of parameters for each model was obtained from the multicurve-fitting procedure. The differences between the glass transition and relaxation parameters were discussed in terms of isomeric effect. The cooperativity determined from curve-fitting results was further compared to those obtained via Donth’s formula.