A dual host approach to NiSO4 extraction

A dual host approach to NiSO4 extraction
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NiSO4 提取的双宿主方法

DOI:
10.1080/10610278.2011.631706
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发表时间:
2012
影响因子:
3.3
通讯作者:
C. Tong
C. Tong
中科院分区:
化学4区
文献类型:
--
作者:
Gareth W. Bates;James E. Davidson;Ross S. Forgan;Philip A. Gale;David K. Henderson;M. King;M. Light;Stephen J. Moore;P. A. Tasker;C. Tong

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本文报道了硫酸盐萃取剂N,N ' -双-(2-二丁基氨基-乙基)-异眼苯酰胺(1)、吡啶-2,6-二羧酸双-[(2-二丁基氨基-乙基)-酰胺](2)和3,4-二苯基- 1h -吡咯-2,5-二羧酸双-[(2-二丁基氨基-乙基)-酰胺](3)的合成,并证明了与市售的肟萃取剂2-羟基-5-壬基苯甲醛肟(P50)结合,与金属盐萃取剂5-壬基-3-二己基氨基甲基-2-羟基苯甲醛肟(4)相比,这些双宿主体系是硫酸盐镍(II)更好的萃取剂。
This paper reports the synthesis of sulphate extractants, N,N′-bis-(2-dibutylamino-ethyl)-isophthalamide (1), pyridine-2,6-dicarboxylic acid bis-[(2-dibutylamino-ethyl)-amide] (2) and 3,4-diphenyl-1H-pyrrole-2,5-dicarboxylic acid bis-[(2-dibutylamino-ethyl)-amide] (3), and demonstrates that, in combination with a commercially available oxime extractant 2-hydroxy-5-nonyl benzaldehyde oxime (P50), these dual host systems are better extractants for nickel(II) sulphate than the metal salt extractant, 5-nonyl-3-dihexylaminomethyl-2-hydroxy-benzaldehyde oxime (4).
DOI: 10.1039/b916877j
发表时间: 2010-01-01
影响因子: 4
作者:
Forgan, Ross S.;Davidson, James E.;White, Fraser J.
通讯作者: White, Fraser J.