On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)
On-surface Ullmann polymerization via intermediate organometallic networks on Ag(111)
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DOI：
10.1039/c4cc02757d
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发表时间：
2014-01-01
影响因子：
4.9
通讯作者：
Lackinger, Markus
中科院分区：
文献类型：
--
作者：
Eichhorn, Johanna;Strunskus, Thomas;Lackinger, Markus
研究了金属有机中间体在银（111）表面乌尔曼偶联聚合中的作用。用x射线光电子能谱（XPS）监测了聚合过程。扫描隧道显微镜（STM）用于表征有机金属和共价键网络，并确定有机金属和共价键形成的温度机制。
The role of organometallic intermediates during on-surface polymerization via Ullmann coupling was studied on Ag(111). The polymerization progress was monitored by X-ray photoelectron spectroscopy (XPS). Scanning Tunneling Microscopy (STM) was used to characterize organometallic and covalent networks and to identify the temperature regimes for organometallic and covalent bond formation.